Preheat oven to 350. Combine flour, 2/3 cup sugar, 1/4 cup cocoa, coffee, baking powder and salt. Mix together milk, butter & vanilla. Add to dry ingredients. Stir well. Spray 8 inch baking pan with nonstick cooking spray. Pour batter into pan. Mix together remaining 1/3 cup sugar & 2 tablespoons cocoa. Sprinkle over batter. Pour 1 cup boiling water over batter. Do not stir. Bake 30 minutes. Serve warm. THE DESSERT SHOW ----